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Regio- and diastereoselective synthesis of cyclic amino esters

✍ Scribed by Kyung-Ho Park; Thomas M Kurth; Marilyn M Olmstead; Mark J Kurth

Book ID
104211711
Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
63 KB
Volume
42
Category
Article
ISSN
0040-4039

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✦ Synopsis

Several cyclic amino esters have been prepared regio-and diastereoselectively depending on the electrophile (cis or trans alkene) and its leaving group.

πŸ“œ SIMILAR VOLUMES

ChemInform Abstract: Regio- and Diastere
ChemInform Abstract: Regio- and Diastereoselective Synthesis of Cyclic Amino Esters.
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Catalytic and chemical reductions of chiral pyrrolidine 13-enamino esters provides corresponding [3-amino esters with good to moderate diastereomer excesses. The unexpected major diastereomer 5 comes from a reduction process which amounts to an anti hydrogen addition.