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Regio- and Diastereoselective Reduction of Nonenolizable α-Diketones to Acyloins Mediated by Indium Metal

✍ Scribed by Khan, Faiz Ahmed; Dash, Jyotirmayee; Sahu, Nilam; Gupta, Sharad


Book ID
127349488
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
57 KB
Volume
4
Category
Article
ISSN
1523-7060

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ChemInform Abstract: Regio- and Diastere
✍ Faiz Ahmed Khan; Jyotirmayee Dash; Nilam Sahu; Sharad Gupta 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 43 KB 👁 1 views

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Indium-Mediated Regio- and Diastereosele
✍ Faiz Ahmed Khan; Jyotirmayee Dash; Ch. Sudheer 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 376 KB 👁 1 views

## Abstract A novel, efficient, and regio‐ as well as diastereoselective conversion of non‐enolizable bicyclic α‐diketones into synthetically useful acyloins mediated by indium metal is described. The reduction is highly diastereoselective, leading exclusively to __endo__‐acyloins (__endo__‐hydroxy