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Regio- and Diastereoselective Reduction of Nonenolizable α-Diketones to Acyloins Mediated by Indium Metal
✍ Scribed by Khan, Faiz Ahmed; Dash, Jyotirmayee; Sahu, Nilam; Gupta, Sharad
- Book ID
- 127349488
- Publisher
- American Chemical Society
- Year
- 2002
- Tongue
- English
- Weight
- 57 KB
- Volume
- 4
- Category
- Article
- ISSN
- 1523-7060
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## Abstract A novel, efficient, and regio‐ as well as diastereoselective conversion of non‐enolizable bicyclic α‐diketones into synthetically useful acyloins mediated by indium metal is described. The reduction is highly diastereoselective, leading exclusively to __endo__‐acyloins (__endo__‐hydroxy
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