Regio- and diastereoselective formation of 1,2-azidohydroperoxides by photooxygenation of alkenes in the presence of azide anions
✍ Scribed by Axel G. Griesbeck; Thomas Hundertmark; Jörg Steinwascher
- Book ID
- 103409097
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- French
- Weight
- 238 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0040-4039
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A convciiicnt "onc-pot" proccdurc for thc synthesis of thc cpoxy alcohols Ic and 2c by photooxygenation of cliolcstcrol (1) in thc presence of Ti(OiPr14 was developed. Thc reaction proceeds rcgioscleciively and stereospecifically. During the photooxygena- iicm or 1 in thc prcsencc of Ti(1V) oxygen t
Z%naary: Treatment of aliphatic ketones with ethyl diazoacetate in the presence of a catalyst results in the regio-and (where appropriate) diastereoseleotive forn'etion of en01 ethers which arise by an intramolecular 1,4-hydrogen shift from an intermediate oarbonyl ylide. Since our original observa
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