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Refinements of the TiNiSi-type RMnSi (R=Tb, Lu, Sc) and DyCoSi structures from single crystal X-ray diffraction

✍ Scribed by I Ijjaali; R Welter; G Venturini; B Malaman


Book ID
117625493
Publisher
Elsevier Science
Year
1999
Tongue
English
Weight
186 KB
Volume
292
Category
Article
ISSN
0925-8388

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The crystal structure determinations and
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A; a ¼ 116:779ð2Þ; b ¼ 96:089ð3Þ; g ¼ 84:000ð3Þ1; R F ¼ 0:033: The disulphate anions are essentially eclipsed. All three structures can be described as dichromate-like, where the alkali cations coordinate oxygens of the isolated disulphate groups in three-dimensional networks. The K-O and Na-O coord