Refinement of the structure of the molecule of 1-silacyclobutane SiH2(CH2)3
β Scribed by V. S. Mastryukov; O. V. Dorofeeva; L. V. Vilkov; B. N. Cyvin; S. J. Cyvin
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 1975
- Tongue
- English
- Weight
- 240 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0022-4766
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π SIMILAR VOLUMES
## Abstract The multipleβchannel reactions SiH~3~ + SiH~3~CH~3~ β products and SiH~3~ + SiH~2~(CH~3~)~2~ β products are investigated by direct dynamics method. The minimum energy path (MEP) is calculated at the MP2/6β31+G(d,p) level, and energetic information is further refined by the MCβQCISD meth
## Abstract Raman spectra of 1,3βdisilabutane (SiH~3~CH~2~SiH~2~CH~3~) as a liquid were recorded at 293 K and as a solid at 78 K. In the Raman cryostat at 78 K an amorphous phase was first formed, giving a spectrum similar to that of the liquid. After annealing to 120 K, the sample crystallized and