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Refined Phase Diagram of Boron Nitride

✍ Scribed by Solozhenko, Vladimir L.; Turkevich, Vladimir Z.; Holzapfel, Wilfried B.

Book ID
121272852
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
35 KB
Volume
103
Category
Article
ISSN
0022-3654

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ChemInform Abstract: Refined Phase Diagr
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Refined Phase Diagram of Boron Nitride. -The equilibrium p,T-diagram of boron nitride is refined on the basis of new experimental data on BN melting and extrapolation of heat capacities of BN polymorphs into the high-temp. region. When compared with the previously calculated diagram, the hBN↔cBN eq

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In order to clarify the discrepancy of the phase diagram on boron nitride as it is found in the literature we have made numerous in situ di4raction experiments using synchrotron radiation. The conditions were temperatures in the range of 16003C and pressures up to 6.5 GPa. For the experiments diamon