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Refined model of optical activity of cis-dihydrodiol metabolites: Role of 1,3-diene conformation in the electronic circular dichroism spectra

✍ Scribed by Marcin Kwit; Jacek Gawronski

Publisher: John Wiley and Sons
Year: 2011
Tongue: English
Weight: 492 KB
Volume: 23
Category: Article
ISSN: 0899-0042
DOI: 10.1002/chir.20974

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## Abstract Absolute configurations of a number of __cis__‐dihydrodiols (__cis__‐1,2‐dihydroxy‐3,5‐cyclohexadienes), synthetically useful products of TDO‐catalyzed dihydroxylations of 1,2‐ and 1,3‐disubstituted benzene derivatives, have been determined by a comparison of calculated and experimental