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Reexamination of Products and the Reaction Mechanism of the Chalcogeno-Baylis–Hillman Reaction: Chalcogenide–TiCl4-mediated Reactions of Electron-Deficient Alkenes with Aldehydes

✍ Scribed by Tadashi Kataoka; Hironori Kinoshita; Tetsuo Iwama; Shin-ichiro Tsujiyama; Tatsunori Iwamura; Shin-ichi Watanabe; Osamu Muraoka; Genzoh Tanabe

Book ID
108370857
Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
149 KB
Volume
56
Category
Article
ISSN
0040-4020

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ChemInform Abstract: Reexamination of Pr
ChemInform Abstract: Reexamination of Products and the Reaction Mechanism of the Chalcogeno-Baylis—Hillman Reaction: Chalcogenide—TiCl4-Mediated Reactions of Electron-Deficient Alkenes with Aldehydes.
✍ Tadashi Kataoka; Hironori Kinoshita; Tetsuo Iwama; Shin-ichiro Tsujiyama; Tatsun 📂 Article 📅 2000 🏛 John Wiley and Sons ⚖ 33 KB 👁 1 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

The chalcogeno-Baylis-Hillman reaction:
The chalcogeno-Baylis-Hillman reaction: a new preparation of allylic alcohols from aldehydes and electron-deficient alkenes
✍ Tadashi Kataoka; Tetsuo Iwama; Shin-ichiro Tsujiyama; Tatsunori Iwamura; Shin-ic 📂 Article 📅 1998 🏛 Elsevier Science 🌐 French ⚖ 841 KB

The chalcogeno-Baylis-Hillman reaction catalyzed by sulfides and selenides, the group 16 element compounds, in the presence of Lewis acids was developed. The reactions proceeded smoothly by the use of 1 equiv of Tic14 to give the coupling products in moderate to good yields. Bischalcogenides and re