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Reduktive Fragmentierung von 1-Methyl-4-tosyloxybicyclo[2.2.2]octan-2-on

✍ Scribed by Dr. W. Kraus

Publisher
John Wiley and Sons
Year
1966
Tongue
English
Weight
204 KB
Volume
78
Category
Article
ISSN
0044-8249

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πŸ“œ SIMILAR VOLUMES

Improved conversion of 6-endo-tosyloxybi
Improved conversion of 6-endo-tosyloxybicyclo[2.2.2]octan-2-ones into 6-exo-acetoxy and 6-exo-benzoyloxybicyclo[2.2.2]octan-2-ones
✍ Rinaldo Marini Bettolo; Luisa Maria Migneco; Piergiogio Moretti; Rita Scarpelli πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 37 KB

The reaction conditions for the conversion of 6endo-tosyloxybicyclo[2.2.2]octan-2-one (7b) into 6-exo-acetoxy (8b) and 6-exo-benzoyloxybicyclo[2.2.2]octan-2-one (8a), respectively, were improved. Thus known 6-endo-tosyloxy-bicyclo[2.2.2]octan-2-ones (+)-(1RS,6SR,8SR,11RS)-11-[(4-toluenesulfonyl)oxy]