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Reductive radical decarboxylation of amino-acids and peptides

✍ Scribed by Barton, Derek H. R.; Herv�, Yolande; Potier, Pierre; Thierry, Josiane

Book ID
120243785
Publisher
The Royal Society of Chemistry
Year
1984
Tongue
English
Weight
172 KB
Volume
0
Category
Article
ISSN
0022-4936

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## Abstract Amino acid and peptide radical cations, M^**.**+^, are formed by oxidative dissociations of [Cu(auxiliary ligand)(M)]^**.**2+^ and [Metal^III^(salen)(M)]^+^ complexes. The most easily formed radicals contain either an aromatic or basic amino acid residue. Aromatic amino acids have low i