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Reductive elimination of dimethylcarbonate from (dimethoxycarbonyl) tricarbonyl cobaltates. Isolation and crystal structures of Cs[Co(COOCH3)2(CO)3] and K[(dibenzo-18-crown-6)][Co(COOCH3)2(CO)3]

✍ Scribed by Giuseppe Fachinetti; Tiziana Funaioli; Dante Masi; Carlo Mealli


Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
254 KB
Volume
417
Category
Article
ISSN
0022-328X

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K 2 W 6 Br 14 (I), Rb 2 W 6 Br 14 (II), and Cs 2 W 6 Br 14 (III) were formed by reactions of W 6 Br 12 with the corresponding alkali metal bromides in evacuated silica tubes with a temperature gradient of 925 K/915 K. (I) crystallizes in the cubic space group Pn3 (no. 201), a = 13.808 A Ê , Z = 4, c