✦ LIBER ✦
Reductive elimination and skeletal rearrangement of β-hydroxy selenide derivatives of bicyclo[4.2.l]nonatriene in a super acid medium
✍ Scribed by Huub M. J. Gillissen; Pieter Schipper; Henk M. Buck
- Book ID
- 104588270
- Publisher
- Elsevier Science
- Year
- 2010
- Tongue
- English
- Weight
- 230 KB
- Volume
- 99
- Category
- Article
- ISSN
- 0165-0513
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✦ Synopsis
Abstract
In sulfur dioxide the β‐hydroxy selenides 1 and 2 produce rearranged selenides 6 and 7 upon addition of fluorosulfonic acid. Reductive elimination and subsequent attack of the selenenyl electrophile on the etheno bridge cause migration of the butadiene moiety.