✦ LIBER ✦

Reductive displacement of allylic acetates by hydride transfer via catalytic activation by palladium(0) complexes

✍ Scribed by Robert O. Hutchins; Keith Learn; Robert P. Fulton

Book ID: 104225953
Publisher: Elsevier Science
Year: 1980
Tongue: French
Weight: 260 KB
Volume: 21
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)93615-3

No coin nor oath required. For personal study only.

✦ Synopsis

Allylic acetates are reduced to alkenes by reductive displacement by hydride reagents via catalytic activation with Pd(0) complexes. In the absence of hydrides, allylic acetates afford conjugated dienes in DMSO solvent.

Under suitable conditions, a number of a-bonded functional groups are susceptible to nucleo-

📜 SIMILAR VOLUMES

Regio- and stereoselective reductive rep

Regio- and stereoselective reductive replacement of allylic oxygen, sulfur, and selenium functional groups by hydride via catalytic activation by palladium(0) complexes

✍ Hutchins, Robert O.; Learn, Keith 📂 Article 📅 1982 🏛 American Chemical Society 🌐 English ⚖ 414 KB

Isomerization of (.pi.-allyl)palladium c

Isomerization of (.pi.-allyl)palladium complexes via nucleophilic displacement by palladium(0). A common mechanism in palladium(0)-catalyzed allylic substitution

✍ Granberg, Kenneth L.; Baeckvall, Jan E. 📂 Article 📅 1992 🏛 American Chemical Society 🌐 English ⚖ 786 KB

Correction. Isomerization of (π-Allyl)Pa

Correction. Isomerization of (π-Allyl)Palladium Complexes via Nucleophilic Displacement by Palladium(0). A Common Mechanism in Palladium(0)-Catalyzed Allylic Substitution

✍ Granberg, Kenneth; Backvall, Jan-E. 📂 Article 📅 1994 🏛 American Chemical Society 🌐 English ⚖ 146 KB