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Reductive Dimerization of Triruthenium Clusters Containing Cationic Aromatic N-Heterocyclic Ligands

✍ Scribed by Javier A. Cabeza; Ignacio del Río; Enrique Pérez-Carreño; Vanessa Pruneda


Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
479 KB
Volume
16
Category
Article
ISSN
0947-6539

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## Abstract The Mannich aminomethylation reaction of aromatic thiols has been used to produce diaza‐18‐crown‐6 ligands containing thiol‐derived side arms. Thiophenols were attached to the azacrown through N‐CH~2~‐S linkages even in the presence of hydroxy or acetamido groups. Heteroaromatic thiols