Reductive dehalogenation of vic-dihaloalkanes to alkenes with sodium sulfide under phase-transfer conditions
โ Scribed by Landini, Dario; Milesi, Luigi; Quadri, Maria Luisa; Rolla, Franco
- Book ID
- 126877052
- Publisher
- American Chemical Society
- Year
- 1984
- Tongue
- English
- Weight
- 266 KB
- Volume
- 49
- Category
- Article
- ISSN
- 0022-3263
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๐ SIMILAR VOLUMES
The reduction of alkyl 2,4+lkadienoates, bearing alkyl substituents on the diene system, with sodium dithionite, under phase transfer conditions, gives satisfactory yields of E:i! isomeric mixtures of the corresponding 3\_alkenoetes, except in the case Gf-the C-2 substituted substrate which afforded
A wide variety of vie-dibromides are debrominated to the corresponding olefins in good to excellent yields by aqueous sodium sulfide or sodium hydrosulfide using trioctylmethylammonium chloride as the phase transfer agent in a two-phase mixture. A. Kaji, Tetrahedron Lett., 1733 (1979). d) Reduction