Reductive cyclization of mercurial enones
โ Scribed by Danishefsky, Samuel; Chackalamannil, Samuel; Uang, Biing Jiun
- Book ID
- 127092595
- Publisher
- American Chemical Society
- Year
- 1982
- Tongue
- English
- Weight
- 272 KB
- Volume
- 47
- Category
- Article
- ISSN
- 0022-3263
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
The titanium-mediated cyclization of d,o-enones by using dichlorotitanium diphenoxide-cyclohexylmagnesium chloride diastereoselectively afforded cis-substituted cyclopentanols and was thus found to parallel the stoichiometric and catalytic titanocene-mediated reactions.
Photoinduced electron transfer / Cyclization f Ring opening / Enones Photolysis of the unsaturated enones 1 yields [2 + 21 cycloaddition products 2 and 3 with varying regioselectivity. Under electron-transfer conditions (PET) spirocyclic products 4 are formed. The straight [2 + 2 1 cycloaddition pro