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Reductive cyclization of mercurial enones

โœ Scribed by Danishefsky, Samuel; Chackalamannil, Samuel; Uang, Biing Jiun


Book ID
127092595
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
272 KB
Volume
47
Category
Article
ISSN
0022-3263

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Photoinduced electron transfer / Cyclization f Ring opening / Enones Photolysis of the unsaturated enones 1 yields [2 + 21 cycloaddition products 2 and 3 with varying regioselectivity. Under electron-transfer conditions (PET) spirocyclic products 4 are formed. The straight [2 + 2 1 cycloaddition pro