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Reductive coupling of aromatic aldehydes and imines by the low valent titanium species generated in the reaction of TiCl4 with Et3N

✍ Scribed by Mariappan Periasamy; Gadthula Srinivas; Galla V Karunakar; Pandi Bharathi

Publisher: Elsevier Science
Year: 1999
Tongue: French
Weight: 207 KB
Volume: 40
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(99)01609-3

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✦ Synopsis

Aromatic aldehydes and imines are converted to the corresponding diols and diamines using the low valent titanium species generated by the reaction of TiC14 with triethylamine.

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