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Reductive Conjugate Addition of Haloalkanes to Enones To Form Silyl Enol Ethers

โœ Scribed by Shrestha, Ruja; Weix, Daniel J.

Book ID
125953184
Publisher
American Chemical Society
Year
2011
Tongue
English
Weight
984 KB
Volume
13
Category
Article
ISSN
1523-7060

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๐Ÿ“œ SIMILAR VOLUMES

The first addition of silyl enol ethers
The first addition of silyl enol ethers to internal unactivated alkynes
โœ Ken-ichiro Imamura; Eiji Yoshikawa; Vladimir Gevorgyan; Yoshinori Yamamoto ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 227 KB

The EtAICl2-mediated intramolecular addition of silyl enol ethers to both terminal and internal unactivated alkyttes, bearing alkyl and phenyl susbstituents at the alkyne moiety, proceeded exclusively in the endo-fashion to give mono-and bicyclic p,T-unsaturated ketones in good to excellent yields.