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Reductive Carbonylation Synthesis of Metal Carbonyls. II. Synthesis of Manganese Carbonyl and Group VI-B Metal Carbonyls by the Alkylaluminum Method 1

✍ Scribed by Podall, Harold E.; Dunn, James H.; Shapiro, Hymin


Book ID
125930447
Publisher
American Chemical Society
Year
1960
Tongue
English
Weight
806 KB
Volume
82
Category
Article
ISSN
0002-7863

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πŸ“œ SIMILAR VOLUMES


Octahedral metal carbonyls. : XXXVII. th
✍ J.E. Pardue; G.R. Dobson πŸ“‚ Article πŸ“… 1976 πŸ› Elsevier Science 🌐 English βš– 503 KB

Studies of the rates of reaction of the Group VI-B metal hexacarbonyls (M = 0, MO, W) with benzylamine, cyclohexylamine and aniline (amine) support a rate law, -d[M(COj6f/dt = kIIM(CO)ej + k2/M(C0)e]famineJ. The rate law is suggestive of two competing mechanisms, with the amine-independent path invo