Reductions of aryl perfluorosulfonates with dimethylamine · borane (Me2NH·BH3) catalyzed by Pd(0): an operationally simple, inexpensive, and general protocol

✍ Scribed by Bruce H. Lipshutz; D.J. Buzard; Randall W. Vivian

• Book ID: 104262038
• Publisher: Elsevier Science
• Year: 1999
• Tongue: French
• Weight: 210 KB
• Volume: 40
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(99)01255-1

✦ Synopsis

Treatment of aryl nonaflates or triflates in CH3CN in the presence of one equivalent of Me2NH. BH3 and K2CO3 leads via Pd(0) catalysis to high yields of reduced arenes.