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Reductions in aprotic media—I. Cathodic reduction limits at a platinum electrode in acetonitrile

✍ Scribed by Stanley Pons; S.B. Khoo


Publisher
Elsevier Science
Year
1982
Tongue
English
Weight
680 KB
Volume
27
Category
Article
ISSN
0013-4686

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✦ Synopsis


The cathodic behavior ofacetonitrile at a platinum electrode is strongly dependent on the cation of the supporting electrolyte, and contamination by moisture. Mixtures of supporting electrolytes can give anomalous effects under certain conditions; the results are consistent with the formation of hydride ion at the platinum surface.


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