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Reduction processes in fast atom bombardment mass spectrometry: Methylene blue in glycerol-thioglycerol and glycerol-nitrobenzyl alcohol matrices

✍ Scribed by Clement W. Kazakoff; Robin T. B. Rye

Publisher
John Wiley and Sons
Year
1991
Tongue
English
Weight
295 KB
Volume
26
Category
Article
ISSN
1076-5174

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✦ Synopsis

Abstract

Reduction of the methylene blue cation during fast atom bombardment was studied in glycerol–thioglycerol and glycerol–nitrobenzyl alcohol matrices. The relative abundances of reduced species are significantly lower in a matrix containing 0.2 m thioglycerol in glycerol than they are in pure thioglycerol. Pure 3‐nitrobenzyl alcohol or a glycerol–nitrobenzyl alcohol mixture is a less effective matrix material. These results are discussed in terms of a postulated mechanism for the formation of the reduced dye cation species.

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