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Reduction potentials and exchange reactions of thiyl radicals and disulfide anion radicals

✍ Scribed by Surdhar, Parminder S.; Armstrong, David A.


Book ID
119958196
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
770 KB
Volume
91
Category
Article
ISSN
0022-3654

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## Abstract The free‐radical addition of 1‐propanethiol, benzenethiol (thiophenol) and α‐toluenethiol (benzyl mercaptan) to allene in benzene solution has been investigated. At high allene/thiol ratios the two sulfides resulting from the addition of one mole of RSH to allene (isopropenyl‐SR and al