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Reduction of β-ketosulfoxides : a highly efficient asymmetric synthesis of both enantiomers of methyl carbinols from the corresponding esters

✍ Scribed by Guy Solladié; Christine Greck; Gilles Demailly; Arlette Solladié-Cavallo


Publisher
Elsevier Science
Year
1982
Tongue
French
Weight
185 KB
Volume
23
Category
Article
ISSN
0040-4039

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## Abstract The insect pheromone (2__R__4__R__6__R__,8__R__)‐4,6,8‐trimethyl‐2‐undecyl formate (lardolure, 7c) and (2__R__,4__R__,6__R__,8__R__)‐4,6,8‐trimethyl‐2‐decyl formate (9‐norlardolure, 7b) have been synthesized from the corresponding homologous chiral methyl‐branched esters 1b and 1c, whic