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Reduction of α,β-unsaturated carbonyl compounds by palladium(II) and nickel(II) complexes having nitrogen-containing ligands

✍ Scribed by Partha P. Jana; Rupam Sarma; Jubaraj B. Baruah


Publisher
Elsevier Science
Year
2008
Tongue
English
Weight
197 KB
Volume
289
Category
Article
ISSN
1381-1169

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A class of cationic dipbosphine complexes of Pt(II) are sufficiently Lewis acidic to catalyze the acetalization of aldehydes and ketones. ~t,l~-Unsaturated substrates can be easily acetalized with ethylene glycol under mild conditions in high yield and avoiding side reactions leading to fomaation of

ChemInform Abstract: Acetalization of α,
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Acetalization of α,β-Unsaturated Carbonyl Compounds Catalyzed by Complexes of Pt(II). -Cationic diphosphine complexes of Pt(II) are sufficiently Lewis acidic to catalyze the acetalization of α,β-unsaturated carbonyl compounds (I) with ethylene glycol. In all cases tested, the Pt-complex displays co