Reduction of α-ω dibromoalkanes on aluminium and mercury cathodes
✍ Scribed by O.R. Brown; E.R. Gonzalez
- Book ID
- 104149646
- Publisher
- Elsevier Science
- Year
- 1973
- Weight
- 593 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0022-0728
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## Abstract Based on the Menschutkin reaction, α,ω‐alkanediamines with α,ω‐dibromoalkanes were employed to synthesize cationic polyelectrolytes named ionenes. By means of __in__‐__situ__ ^13^C NMR we have characterized the influence of ionic charges on the reactivity of the polymerizing species. Th
It appears that indan l-ones may have a rather unforeseencathodic behaviour when substituted in cl-position by a hydroxy group, with formation of a stereospecifrc tetraol by coupling. Such a dimer was also obtained by means ofa one-step mixed electrolysis of the corresponding indanones in the presen