Reduction of Unsaturated 1,4-Diketones by Aluminum Isopropoxide 1
β Scribed by Lutz, Robert E.; Gillespie, J. S.
- Book ID
- 126258419
- Publisher
- American Chemical Society
- Year
- 1950
- Tongue
- English
- Weight
- 396 KB
- Volume
- 72
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
A new synthetic route to C2-symmetric chiral 1,4-diols based on the borane-mediated oxazaborolidine-catalysed reduction of 2-ene-l,4-diones (2), of 2-yne-l,4-diones (3), and/or of Cocomplexed diketones 4 is described. Good to excellent enantio-and diastereoselectivities have been obtained in the red
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