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Reduction of S−3 and S2−6 polysulfide ions in liquid ammonia

✍ Scribed by E. Levillain; A. Demortier; J.P. Lelieur


Publisher
Elsevier
Year
1995
Tongue
English
Weight
467 KB
Volume
394
Category
Article
ISSN
1572-6657

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Synthesis of (RSn)4X6 Adamantanes (X = O
✍ Karsten Wraage; Thomas Pape; Regine Herbst-Irmer; Mathias Noltemeyer; Hans-G. Sc 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 266 KB

The reactions of trisSnBr 3 (1) [tris = (Me 3 Si) 3 C] and nBuSnCl 3 pressure at room temperature results in the formation of (trisSn) 4 S 6 (3) and (trisSn) 4 Se 6 (4). nBuSnCl 3 reacts with Na 2 S with Na 2 X (X = O, S, Se) yield the heterocyclic adamantanes 2-6. The reaction of 1 with Na 2 O is c