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Reduction of Rhodium(III) Porphyrin Hydroxide to Rhodium(II) Porphyrin

✍ Scribed by Choi, Kwong Shing; Lai, Tsz Ho; Lee, Siu Yin; Chan, Kin Shing

Book ID
120817560
Publisher
American Chemical Society
Year
2011
Tongue
English
Weight
968 KB
Volume
30
Category
Article
ISSN
0276-7333

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Luminescence and triplet—triplet absorpt
Luminescence and triplet—triplet absorption spectra of rhodium (III) porphyrins
✍ K. Kalyanasundaram 📂 Article 📅 1984 🏛 Elsevier Science 🌐 English ⚖ 583 KB

Photophysical studies of four rhodium(I11) porphyrins [ RhTPPS (H20):-, RhTPPKl) CL), RhOEP(C11 (L) and RhMesoPhlE(Cl)(L)] show that these porphyrins are characterised by a moderate phosphorescence (0 > lo-\*) and avery weak fluorescence (@I Q 5 x 10d4) in solution at room temperature. TPP derivativ