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Reduction of redox mediators by CO in the presence of a Co porphyrin: Implication for electrochemical cells powered by CO

✍ Scribed by Yamazaki, Shin-ichi; Siroma, Zyun; Yao, Masaru; Fujiwara, Naoko; Asahi, Masafumi; Ioroi, Tsutomu

Book ID
120069426
Publisher
Elsevier Science
Year
2013
Tongue
English
Weight
525 KB
Volume
235
Category
Article
ISSN
0378-7753

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The electrochemical properties of the redox mediator Co(III)/Co(II)(dbbip) 2 (dbbip = 2,6-bis(1 -butylbenzimidazol-2 -yl)pyridine) in a mixed acetonitrile/ethylene carbonate solvent have been studied by a range of techniques in order to determine the rate constants for electron transfer and the diff