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Reduction of quinoline and isoquinoline with sodium hydride

โœ Scribed by Mitsutaka Natsume; Setsuko Kumadaki; Yoshihiro Kanda; Kazuko Kiuchi


Book ID
104247144
Publisher
Elsevier Science
Year
1973
Tongue
French
Weight
228 KB
Volume
14
Category
Article
ISSN
0040-4039

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โœฆ Synopsis


Sodium hydride is highly appreciated as one of very good bases, and reduction with this reagent seldom occura except in special compound8 having a structure of benzyl halides,') non-enolizable carbonyls, 2) gem-dihalocyclopropanes,3) and aisulfiae4) moieties. We wish to report here another instance of this reduction,


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Reductive cleavage of t-butyldimethylsil
โœ Mohammed Salehpp Shekhani; Khalid Mohammed Khan; Khalid Mahmood ๐Ÿ“‚ Article ๐Ÿ“… 1988 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 133 KB

t\_Butyldimethylsilyl ethers are cleaved with sodium hydride in hexamethylphosphoric triamide (HMPA) or N ,N'-dimethylpropyleneurea (DMPU).