✦ LIBER ✦

Reduction of pentachlorotantalum in pure trimethylphosphine: the synthesis of compounds containing the Ta-η2-CHPMe2 group: crystal structure of [Ta(η2-CHPMe2)(η-C4H6)(PMe3)2Cl]

✍ Scribed by Malcolm L.H. Green; Phillip M. Hare; Judith A. Bandy

Publisher: Elsevier Science
Year: 1987
Tongue: English
Weight: 1000 KB
Volume: 330
Category: Article
ISSN: 0022-328X
DOI: 10.1016/0022-328x(87)80278-4

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

An unusual double CH activation of coor

An unusual double CH activation of coordinated trimethylphosphine. Synthesis, molecular structure and reactivity of (C5Me5)Ta(PMe3)(H)2(η2-CHPMe2)

✍ Terence P. Kee; Vernon C. Gibson; William Clegg 📂 Article 📅 1987 🏛 Elsevier Science 🌐 English ⚖ 312 KB

Reactions of (η5-C5Me5)Ta(PMe3)(H)2(η2 C

Reactions of (η5-C5Me5)Ta(PMe3)(H)2(η2 CHPMe2) with heterocumulenes and the interconversion of tautomeric formamido complexes of tantalum

✍ Vernon C. Gibson; Terence P. Kee 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 415 KB

Convenient one-pot synthesis of half-san

Convenient one-pot synthesis of half-sandwich η-cycloheptatrienyl and η-toluene derivatives of the metals titanium and zirconium; crystal structure of [Zr(η6-C6H5Me)(PMe3)2Cl2]

✍ Gary M. Diamond; Malcolm L.H. Green; Neil M. Walker 📂 Article 📅 1991 🏛 Elsevier Science 🌐 English ⚖ 240 KB

Synthesis, Structural Characterisation a

Synthesis, Structural Characterisation and Reactivity of New Dinuclear Monocyclopentadienyl Imidoniobium and -tantalum Complexes − X-ray Crystal Structures of [{Nb(η5-C5H4SiMe3)Cl2}2(μ-1,4-NC6H4N)], [{Ta(η5-C5Me5)Cl2}2(μ-1,4-NC6H4N)] and [{Ta(η5-C5Me5)(CH2SiMe3)2}2(μ-1,4-NC6H4N)]

✍ Antonio Antiñolo; Iván Dorado; Mariano Fajardo; Andrés Garcés; Isabel López-Sol 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 254 KB 👁 1 views

## Abstract The preparation of a family of dinuclear monocyclopentadienyl imidoniobium and ‐tantalum complexes was achieved by two different synthetic routes. The diimido complexes [{M(Cp′)Cl~2~}~2~(μ‐1,__i__‐NC~6~H~4~N)] [Cp′ = η^5^‐C~5~H~4~SiMe~3~, M = Nb, __i__ = 4 (1); Cp′ = η^5^‐C~5~H~4~SiMe~3

Synthesis of mono- and bimetallic ruthen

Synthesis of mono- and bimetallic ruthenium carbonyl compounds from ring-coupled bis(cyclopentadienyl thallium) reagents. The molecular structures of [Ru(CO)2][Ru(CO)2Cl][η5, η5:η1-C5H4(CH2)2CC5H3], Ru2(CO)4[η5, η5-C5H4(CH3)2SiC5H4] and [Ru(CO)2Br][Ru(CO)2Cl][η5, η5-C5H4C2H4C5H4]

✍ Thomas E. Bitterwolf; Maureen B. Leonard; Pamela A. Horine; Joyce E. Shade; Arno 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 834 KB

The synthesis, characterization and poly

The synthesis, characterization and polycondensation of metal-containing diols: crystal structure of [(η5-C5H5)(CO)2Fe(CH2)3O-{2,6-(CH2OH)2-4-CH3C6H2}]

✍ S. F. Mapolie; I. J. Mavunkal; J. R. Moss; G. S. Smith 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 156 KB 👁 3 views