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Reduction of NO by CO on Unsupported Ir: Bridging the Materials Gap

✍ Scribed by Wenhua Chen; Quantong Shen; Robert A. Bartynski; Payam Kaghazchi; Timo Jacob

Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
230 KB
Volume
11
Category
Article
ISSN
1439-4235

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It was found that the catalytic activity and selectivity of Pd for the reduction of NO by CO at temperatures of 600 to 750 K can be markedly and reversibly affected by depositing a polycrystalline Pd film on 8 mol% Y 2 O 3 -stabilized-ZrO 2 (YSZ), an O 2-conductor, and applying external negative cur

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The reaction system NO-NH,-O,-CO was investigated in a tubular flow reactor. The dependence of the fractional conversions of NO, NH, and CO was measured as a function of residence time, temperature, initial NHJNO molar ratio and concentrations of CO and Oz. Addition of CO promotes the reaction and s