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Reduction of methyl benzoylformate by reduced nicotinamide adenine dinucleotide model in the presence of rhodizonic acid

✍ Scribed by Takeshi Endo; Tadayoshi Takada; Makoto Okawara

Publisher: Elsevier Science
Year: 1986
Tongue: French
Weight: 198 KB
Volume: 27
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)84055-1

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✦ Synopsis

Summarv: The reduction of rhodizonic acid(RA) with 1-benzyl-1,4-dihydronicotinamide(BNAH; NADH model) was carried out at room temperature to obtain tetrahydroxy-p-quinone(THQ) and hexahydroxybenzene(HHB) by two-electron and fourelectron-reductions,respectively. The reduction of methyl benzoylformate with BNAH proceeded smoothly in the presence of RA, although it could not be reduced at all without RA.

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