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Reduction of Ketones with Hydrocarbon-Soluble Calcium Hydride: Stoichiometric Reactions and Catalytic Hydrosilylation

โœ Scribed by Jan Spielmann; Sjoerd Harder


Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
323 KB
Volume
2008
Category
Article
ISSN
1434-1948

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5.00 (q, J = 6.5, CHCH,); arom. H's hidden. I3C-NMR (C6D6): 24.7 (CH,); 69.5 ( C H C H ? ) ; 119.8 (C(5')); 121.7 (C(3')); 136.4 (C(4')); 148.4 (C(6')); C(2') not observed. ## ') An alternative mechanism, that cannot be excluded, involves the intermediacy of a metallo-ester, formed by a reversibl