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Reduction of iminium ethers with sodium boro[3H] hydride. Preparation of tritium labelled clomiphene and nitromiphene (CI 628)

✍ Scribed by Peter C. Ruenitz; Jerome R. Bagley


Publisher
John Wiley and Sons
Year
1984
Tongue
French
Weight
248 KB
Volume
21
Category
Article
ISSN
0022-2135

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✦ Synopsis


3

3 The preparation of [ HI-clomiphene and [ HI-nitromiphene fro NaB H is described. The radiochemical yield and specific activlty of the former are 34% and 16 mCi/mmol and those of the latter were 42% and 20 mCi/mmol, respectively. The method described is of micromolar scale designed for maintaining cost economy in the purchase of expensive radiolabelled reagents while yielding final products of sufficient radioactivity for in vitro and in vivo metabolism studies.