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Reduction of gem-dibromocyclopropanes with chromium(II) sulphate

✍ Scribed by H. Nozaki; T. Aratani; R. Noyori


Publisher
Elsevier Science
Year
1967
Tongue
French
Weight
435 KB
Volume
23
Category
Article
ISSN
0040-4020

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Reaction of gem-Dibromocyclopropanes or
✍ Hirotada Kakiya; Rie Inoue; Hiroshi Shinokubo; Koichiro Oshima πŸ“‚ Article πŸ“… 2000 πŸ› Elsevier Science 🌐 French βš– 165 KB

AbstractÐTreatment of gem-dibromocyclopropanes with trialkylmanganate, derived from manganese(II) chloride and three equivalents of Grignard reagent or alkyllithium, followed by an addition of electrophiles provided dialkylated cyclopropanes in good yields. It was found that the reaction of gem-dibr