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Reduction of carbonyl compounds via hydrosilylation : I. Hydrosilylation of carbonyl compounds catalyzed by tris(triphenylphosphine)chlororhodium

โœ Scribed by Iwao Ojima; Mitsuru Nihonyanagi; Tetsuo Kogure; Miyoko Kumagai; Shuji Horiuchi; Kimiyo Nakatsugawa; Yoichiro Nagai


Book ID
108347124
Publisher
Elsevier Science
Year
1975
Tongue
English
Weight
999 KB
Volume
94
Category
Article
ISSN
0022-328X

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Hydrosilylation of carbonyl compounds ca
โœ Yusuke Izumi; Hiroyuki Nanami; Katsumi Higuchi; Makoto Onaka ๐Ÿ“‚ Article ๐Ÿ“… 1991 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 248 KB

Hydrosilylation of carbonyl compounds with hydmsilane is efficiently catalyzed by inorganic solid acids and bases such as Fe 3+ ion-exchanged montmorillonite and hydmxyapatite (Calo(P04)s(OH)2) at reaction temperatures between 25 and 90 OC. Enones are also selectively hydmsilylated in the presence o