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Reduction of [(C5Me5)2Mo2O5] and [(C5Me5)2Mo2O4] in Methanol/Water/Trifluoroacetate Solutions Investigated by Combined On-Line Electrochemistry/Electrospray-Ionization Mass Spectrometry

✍ Scribed by Jenny Gun; Alexandre Modestov; Ovadia Lev; Rinaldo Poli


Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
242 KB
Volume
2003
Category
Article
ISSN
1434-1948

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Synthesis and Structure of the Tetrameri
✍ Haijun Hao; Herbert W. Roesky; Chunming Cui; Hans-Georg Schmidt; Mathias Nolteme 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 German ⚖ 160 KB 👁 1 views

Treating [Cp\*V(l-Cl) 2 ] 3 (Cp\* = C 5 Me 5 ) and [(2,6-i-Pr 2 C 6 H 3 N) 2 MoMe 2 ], respectively, with Me 3 SnF afforded the title compounds [Cp\*V(l-F) 2 ] 4 (1) and [(2,6-i-Pr 2 C 6 H 3 N) 2 MoF 2 ] ´THF ( 2). 1 has a tetrameric structure, in which four V atoms can be regarded as being arranged