Reduction of bromine(V) by cerium(III), manganese(II), and neptunium(V) in aqueous sulfuric acid
โ Scribed by Thompson, Richard C.
- Book ID
- 126223821
- Publisher
- American Chemical Society
- Year
- 1971
- Tongue
- English
- Weight
- 146 KB
- Volume
- 93
- Category
- Article
- ISSN
- 0002-7863
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Manganese(II) is oxidized by ozone in acid solution, k ฯญ (1.5 ฯฎ 0.2) ฯซ in HClO 4 and in H 2 SO 4 . The plausible mechanism is 3 ฯช1 ฯช1 3 ฯช 1 ฯช 1 10 M s k ฯญ (1.8 ฯฎ 0.2) ฯซ 10 M s an oxygen atom transfer from O 3 to producing the manganyl ion which subse-2ฯฉ 2ฯฉ Mn MnO , quently reacts rapidly with to for
## Abstract The oxidation of Dโmannitol by cerium(IV) has been studied spectrophotometrically in aqueous sulfuric acid medium at 25ยฐC at constant ionic strength of 1.60 mol dm^โ3^. A microamount of ruthenium(III) (10^โ6^ mol dm^โ3^) is sufficient to enhance the slow reaction between Dโmannitol and
The kinetics of oxidation of ethanol by cerium(1V) in presence of ruthenium(II1) (in the order of mol dm-3) in aqueous sulfuric acid media have been followed at different temperatures (25-40ยฐC). The rate of disappearance of cerium(1V) in the title reaction increases sharply with increasing [CzH50H]