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Reduction of benzophenone with metal hydrides. A kinetic isotope effect and substituent effect study

โœ Scribed by Yamataka, Hiroshi; Hanafusa, Terukiyo

Book ID
127381596
Publisher
American Chemical Society
Year
1988
Tongue
English
Weight
673 KB
Volume
53
Category
Article
ISSN
0022-3263

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โœ Takashi Kamitanaka; Tomoko Matsuda; Tadao Harada ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 105 KB

The reductions of several substituted acetophenones using supercritical 2-propanol were carried out to estimate the Hammett's reaction constant (z=0.33). Also, the reduction of acetophenone using supercritical deuteriated 2-propanol was carried out to determine the rate-determining step. The kinetic