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Reduction of Aromatic and Aliphatic Esters Using the Reducing Systems MoO2(acac)2 or V(O)(OiPr)3 in Combination with 1,1,3,3-Tetramethyldisiloxane

✍ Scribed by Leyla Pehlivan; Estelle Métay; Stéphane Laval; Wissam Dayoub; Dominique Delbrayelle; Gérard Mignani; Marc Lemaire

Publisher: John Wiley and Sons
Year: 2011
Tongue: English
Weight: 426 KB
Volume: 2011
Category: Article
ISSN: 1434-193X
DOI: 10.1002/ejoc.201101016

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✦ Synopsis

Abstract

An efficient reduction of aromatic and aliphatic esters with 1,1,3,3‐tetramethyldisiloxane in combination with [MoO~2~(acac)~2~] or [V(O)(O__i__Pr)~3~] is reported. In the former system, the presence of triphenylphosphane oxide allows high conversion and good isolated yield to be reached. For the latter system, no ligand is necessary to obtain the corresponding alcohols with similar results.

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