Reduction of aliphatic nitramines. Approach to the synthesis of nitrosamines and amines
✍ Scribed by Pedro de Armas; Cosme G Francisco; Rosendo Hernández; Ernesto Suárez
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- French
- Weight
- 186 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0040-4039
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📜 SIMILAR VOLUMES
In the presence of ultrasound various mono-, di-, and a$-unsaturated cyanides were reduced with Cu-A1 alloy in NaOD-DzO and THF to the corresponding deuteriated aliphatic amines, such as nonylamines, Putrescine, and 1,6-hexanediamine, in high deuterium content.
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Amine N-oxides have been observed to be reduced by titanium(II1) chloride. To study this reaction, 24 model amine N-oxides were reacted with titanium(II1) chloride. The products of these reactions were shown by melting (boiling) points, mixed melting points, derivatives, refractive indices, infrared