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Reduction of acids at a platinum ultramicroelectrode: application to “in situ” acid number control of fluid lubricants (phosphate esters)

✍ Scribed by M. Perdicakis; C. Piatnicki; M. Sadik; R. Pasturaud; B. Benzakour; J. Bessière


Book ID
102982810
Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
830 KB
Volume
273
Category
Article
ISSN
0003-2670

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✦ Synopsis


AbStlYKt

The strength of acids, then charge and possibly thew behawour as polyaclds can be deduced by companng theu hnutmg currents at a platmum ultranucroelectrode m the absence and presence of an excess of supportmg electrolyte Acid-base reactlons m tnbutyl phosphate can be followed wthout deliberately added supportmg electrolyte even If then-dlelectnc constant 1s low The acidity of phosphate esters resulting from theu hydrolysis can be momtored by amperometry at a platmum ultranucroelectrode