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Reduction of 1-alkoxy- and 1-aryloxy-2,2-dichlorocyclopropanes

✍ Scribed by A. A. Retinskii; S. M. Shostakovskii

Book ID
112435497
Publisher
Springer
Year
1967
Tongue
English
Weight
136 KB
Volume
16
Category
Article
ISSN
1573-9171

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Generation and Trapping of Cyclopropenes
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✍ Paul Müller; Nicole Pautex 📂 Article 📅 1991 🏛 John Wiley and Sons 🌐 German ⚖ 597 KB

## Abstract In presence of crown ether, 2‐alkoxy‐1,1‐dichlorocyclopropanes react with __t__‐BuOK/THF preferentially __via__ ring opening to 2‐chloroalk‐2‐en‐1‐ones and alkynones or to chlorocyclopropenes. The latter may be intercepted with 1,3‐diphenylisobenzofuran, but in the absence of trapping a