Reduction of 1-(2-bromophenyl)-1,2,2-triphenylethylene by naphthalene radical anion
β Scribed by Roderic P. Quirk; Frank H. Murphy
- Book ID
- 104237528
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- French
- Weight
- 211 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
β¦ Synopsis
The mechanism of reduction of halobenzenes by naphthalene radical anions is a matter of current interest and controversy 12 . As part of our continuing interest in utilizing intra- molecular rearrangement reactions as probes for radical intermediates 3-5 , the reduction of 1-(P-bromophenyl)-1,2,2-triphenylethylene6
(1) by the naphthalene radical anion has been investigated.
π SIMILAR VOLUMES
## Abstract ESR. and ENDOR. studies are reported for the radical anions of 1,2βdiphenylcyclopentene (**3**) and its di(pe+deuteriophenyl)βderivative (3βD~10~). Comparison of the coupling constants of the phenyl protons in **3**\documentclass{article}\pagestyle{empty}\begin{document}$ ^{\ominus \ato
The circular dichrokm and electronic spectra of the 2,2'dimethyl-l,l'-binaphthyl anion radical have been studied. The assimments of the complicated absorption bands of :hespecies were made with theaid of the s&s in the circular dichroism spectrum and the dihedral angle of the anion radical was set i