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Reduction-elimination of cyclic phosphate derivatives as a route to alkenes

✍ Scribed by Marshall, James A.; Lewellyn, Morris E.

Book ID
126419176
Publisher
American Chemical Society
Year
1977
Tongue
English
Weight
693 KB
Volume
42
Category
Article
ISSN
0022-3263

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Palladium-catalyzed cyclizadon of appropriately structured triynes, haloalkenyldiynes, or haloalkenylalkyne-alkyne mixtures can provide the corresponding benzene derivatives, while the Pd-catalyzed intermolecular reaction of diynes with alkenyl halides can give fulvene derivatives. Cascade cat%opaI