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Reduction and oxidation of carbon-carbon double bonds of 1,1,4,4-tetrakis(trimethylsilyl)butatriene

โœ Scribed by Tetsuo Kusumoto; Tamejiro Hiyama

Book ID
104227179
Publisher
Elsevier Science
Year
1987
Tongue
French
Weight
141 KB
Volume
28
Category
Article
ISSN
0040-4039

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Preparation and reactions of 1,1,4,4-tet
Preparation and reactions of 1,1,4,4-tetrakis(trimethylsilyl)butane-1,4-diyl dianion
โœ Mitsuo Kira; Takakazu Hino; Yasushi Kubota; Naoko Matsuyama; Hideki Sakurai ๐Ÿ“‚ Article ๐Ÿ“… 1988 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 262 KB

Reduction of l,l-bis(trimethylsilyl)ethylene by alkali metal led to the facile dimerization to the 1,1,4,4-tetrakis(trimethylsilyl)butane-1,4-diyl dianion which has been found to be utilized as a reagent for the Peterson reaction.