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Reduction and dissolution of manganese(III) and manganese(IV) oxides by organics. 1. Reaction with hydroquinone

โœ Scribed by Stone, Alan T.; Morgan, James J.


Book ID
120386785
Publisher
American Chemical Society
Year
1984
Tongue
English
Weight
895 KB
Volume
18
Category
Article
ISSN
0013-936X

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Manganese(II) is oxidized by ozone in acid solution, k ฯญ (1.5 ฯฎ 0.2) ฯซ in HClO 4 and in H 2 SO 4 . The plausible mechanism is 3 ฯช1 ฯช1 3 ฯช 1 ฯช 1 10 M s k ฯญ (1.8 ฯฎ 0.2) ฯซ 10 M s an oxygen atom transfer from O 3 to producing the manganyl ion which subse-2ฯฉ 2ฯฉ Mn MnO , quently reacts rapidly with to for