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Reductibility and spectroscopic behaviour of the (NH4)4[H6CuMo6O24] · 4H2O anderson phase

✍ Scribed by I.L. Botto; C.I. Cabello; G. Minelli; M. Occhiuzzi

Book ID
113300408
Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
918 KB
Volume
39
Category
Article
ISSN
0254-0584

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Tetraammonium hexa­hydrogen hexamolybdon
Tetraammonium hexa­hydrogen hexamolybdonickel­ate(II) tetrahydrate, (NH4)4[H6NiMo6O24]·4H2O
✍ Lee, Uk ;Joo, Hea-Chung ;Kwon, Jae-Sam 📂 Article 📅 2001 🏛 International Union of Crystallography 🌐 English ⚖ 271 KB

Crystals of the title compound, (NH 4 ) 4 [H 6 NiMo 6 O 24 ]Á4H 2 O containing the well known B-type Anderson±Evans heteropolyoxometalate, were obtained by recrystallization of powder (NH 4 ) 4 [H 6 NiMo 6 O 24 ]ÁnH 2 O. The anion has the Ni atom at an inversion center and has close to 3m symmetry,